Abstract
The research for three-dimension (3D) printing carbon and carbide energy storage devices has attracted widespread exploration interests. Being designable in structure and materials, graphene oxide (GO) and MXene accompanied with a direct ink writing exhibit a promising prospect for constructing high areal and volume energy density devices. This review not only summarizes the recent advances in 3D printing energy storage devices including printing methods, ink rheological properties, and different energy storage systems, but also discusses the printing methods related to energy storage. In addition, the binder or additive free of two-dimensional carbide materials is quite important for the present electrochemical energy storage devices, which also are presented.